Tricarbonate
Names | |
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IUPAC name Tricarbonate | |
Properties | |
Chemical formula | C3O2−7 |
Molar mass | 148.026 g·mol−1 |
Structure | |
Molecular shape | Trigonal planar at carbon atoms |
Related compounds | |
Related compounds |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
In organic chemistry, a tricarbonate is a compound containing the divalent −O−C(=O)−O−C(=O)−O−C(=O)−O− functional group, which consists of three carbonate groups linked in a chain by sharing of oxygen atoms. These compounds can be viewed as derivatives of a hypothetical tricarbonic acid, HO−C(=O)−O−C(=O)−O−C(=O)−OH. An important example is di-tert-butyl tricarbonate (H3C−)3C−C3O7−C(−CH3)3, an intermediate in the synthesis of di-tert-butyl dicarbonate.[1]
The term tricarbonate is sometimes used for salts that contain three carbonate dianions in their covalent structure or stoichiometric formula, such as cerium tricarbonate Ce2(CO3)3.
See also
- Dicarbonate
References
- ^ Barry M. Pope, Yutaka Yamamoto, and D. Stanley Tarbell (1977), "Di-tert-Butyl Dicarbonate". Organic Syntheses, Vol. 57, p.45; Coll. Vol. 6 (1988) p.418
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- CO
- CO2
- CO3
- CO4
- CO5
- CO6
- C2O
- C2O2
- C2O3
- C2O4 (1,2-Dioxetanedione and 1,3-Dioxetanedione)
- C3O
- C3O2
- C3O3
- C3O6
- C4O2
- C4O4
- C4O6
- C5O2
- C5O5
- C6O6 (Cyclohexanehexone and Ethylenetetracarboxylic dianhydride)
- C8O8
- C9O9
- C10O8
- C10O10
- C12O6
- C12O9
- C12O12
- Graphite oxide
- C3O2
- CO
- CO2
- Metal carbonyls
- Carbonic acid
- Bicarbonates
- Carbonates
- Polycarbonates (Dicarbonates and Tricarbonates)
- Peroxydicarbonates
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