Lithium hypofluorite
Names | |
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Preferred IUPAC name Lithium hypofluorite | |
Other names Lithium fluoride oxide, lithium oxyfluoride | |
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InChI
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Properties | |
Chemical formula | LiOF |
Molar mass | 41.94 g·mol−1 |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
Chemical compound
Lithium hypofluorite is an inorganic compound with the chemical formula of LiOF. It is a compound of lithium, fluorine, and oxygen.[1][2][3] This is a lithium salt of hypofluorous acid.[4], and contains lithium cations Li+ and hypofluorite anions −OF.
Synthesis
The salt theoretically results from the neutralization of hypofluorous acid (HOF) and lithium hydroxide (LiOH). It can be formed by the action of fluorine on lithium hydroxide:
- 6 F2 + 6 LiOH → 2 LiF + O2 + 4 LiOF + 6 HF
Chemical properties
The compound is quite unstable, since it contains oxygen in the oxidation state of 0. It, therefore, tends to decompose to lithium fluoride and oxygen gas:
- 2 LiOF → 2 LiF + O2
References
- ^ Science Data Booklet. Manjunath.R. 11 July 2020. p. 146. Retrieved 12 May 2023.
- ^ Barin, Ihsan (1995). Thermochemical Data of Pure Substances: La-Zr. VCH. p. 965. ISBN 978-3-527-28745-1. Retrieved 12 May 2023.
- ^ Binnewies, M.; Milke, E. (3 December 2002). Thermochemical Data of Elements and Compounds. Wiley. p. 466. ISBN 978-3-527-30524-7. Retrieved 12 May 2023.
- ^ "NIST-JANAF Themochemical Tables, Fourth Edition". NIST. 1998. pp. 1–1951. Retrieved 12 May 2023.
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- LiBr
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- LiBrO
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- Li3F6Al
- FLiBe
- LiFePO4
- FLiNaK
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- Li2GeO3
- LiGe2(PO4)3
- LiH
- LiH2AsO4
- Li2HAsO4
- LiHCO3
- Li3H(CO3)2
- LiH2PO3
- LiH2PO4
- LiHSO3
- LiHSO4
- LiHe
- LiI
- LiIO
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- LiIO3
- LiIO4
- Li2IrO3
- Li7La3Zr2O12
- LiMn2O4
- Li2MoO4
- Li0.9Mo6O17
- LiN3
- Li3N
- LiNH2
- Li2NH
- LiNO2
- LiNO3
- LiNO3·H2O
- Li2N2O2
- LiNa
- Li2NaPO3
- LiNaNO2
- LiNbO3
- Li2NbO3
- LiO−
- LiO2
- LiO3
- Li2O
- Li2O2
- LiOH
- Li3P
- LiPF6
- Li3PO4
- Li2HPO3
- Li2HPO4
- Li3PO3
- Li3PO4
- Li2Po
- Li2PtO3
- Li2RuO3
- Li2S
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- LiSH
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- Li2SO3
- Li2SO4
- Li[SbF6]
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- Li2SeO3
- Li2SeO4
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- Li4SiO4
- Li2SiO3
- Li2Si2O5
- LiTaO3
- Li2Te
- LiTe3
- Li2TeO3
- Li2TeO4
- Li2TiO3
- Li4Ti5O12
- LiTi2(PO4)3
- LiVO3·2H2O
- Li3V2(PO4)3
- Li2WO4
- LiYF4
- LiZr2(PO4)3
- Li2ZrO3
- Hemolithin (extraterrestrial protein)
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- LiC2F6NO4S2
- LiN(SiMe3)2
- Li3C6H5O7
- C5H5Li
- LiN(C3H7)2
- (C6H5)2PLi
- C18H35LiO3
- C6H13Li
- C4H9Li
- CH3CHLiCH2CH3
- (CH3)3CLi
- C12H28BLi
- CH3Li
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- C5H11Li
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- C6H5Li
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- LiO2C(CH2)16CH3
- C4H5LiO4
- LiEt3BH
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- Hsianghualite
- Jadarite LiNaSiB3O7OH
- Keatite Li(AlSi2O6)
- Kunzite
- Lavinskyite
- Lepidolite
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- Manandonite
- Manganoneptunite
- Nambulite
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- Pezzottaite Cs(Be2Li)Al2Si6O18
- Rossmanite
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- Spodumene LiAl(SiO3)2
- Sugilite
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- Tourmaline
- Triphylite LiFePO4
- Zabuyelite Li2CO3
- Zektzerite
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- LixBey
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- LiFHeO
- LiHe2
- (HeO)(LiF)2
- La2/3-xLi3xTiO3He
- Aluminium–lithium alloys
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- LB buffer
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- Lithium soap
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